Efficient Polymer-Polymer Conjugation via Thiol-ene Click Reaction
نویسندگان
چکیده
منابع مشابه
Preparation and Preliminary Dielectric Characterization of Structured C60-Thiol-Ene Polymer Nanocomposites Assembled Using the Thiol-Ene Click Reaction
Fullerene-containing materials have the ability to store and release electrical energy. Therefore, fullerenes may ultimately find use in high-voltage equipment devices or as super capacitors for high electric energy storage due to this ease of manipulating their excellent dielectric properties and their high volume resistivity. A series of structured fullerene (C60) polymer nanocomposites were ...
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To fabricate molecularly imprinted polymer nanospheres via click reaction, five different clickable compounds were synthesized and two types of click reactions (azide-alkyne and thiol-yne) were explored. It was found that molecularly imprinted polymer nanospheres could be successfully synthesized via thiol-yne click reaction using 3,5-diethynyl-pyridine (1) as the monomer, tris(3-mercaptopropio...
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Syndiotactic 1,2 polybutadiene nanoparticles (volume average diameter 13 nm) were func tionalized in aqueous dispersion by free radical mercaptan addition. By appropriate choice of both water soluble radical initiator andmercaptan concentration, nanoparticles with a degree of functionalization of up to 85% were prepared using 3 mercaptopropionic acid methyl ester and 3 mercaptopropionic acid. O...
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Towards the development of (bio)degradable polymers with medical relevance a non-radical thiolene synthesis route is investigated. In this work, step growth polymerization based on Michael addition click reactions is presented. Homotelechelic RAFT polymers were conjugated leading to polymers with molar weight distribution typical for a step growth polymerization, tailing up to 100 000 g∙mol-1 i...
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Conjugated microporous polymers (CMPs) are materials of low density and high intrinsic porosity. This is due to the use of rigid building blocks consisting only of lightweight elements. These materials are usually stable up to temperatures of 400 °C and are chemically inert, since the networks are highly crosslinked via strong covalent bonds, making them ideal candidates for demanding applicati...
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ژورنال
عنوان ژورنال: Macromolecular Chemistry and Physics
سال: 2017
ISSN: 1022-1352
DOI: 10.1002/macp.201700073